电厂屏式过热器弯头开裂原因失效分析

通过外观检查、硬度、金相等检测方法,从金属管壁超温运行、蒸汽侧氧化行为、析出相及冷弯变形对组织性能影响等方面分析了某电厂1 000 MW超超临界机组屏式过热器弯头开裂原因,得出TP347HFG弯头开裂的主要原因是弯头组织富含较多的σ相、NbC等硬脆析出相,同时冷弯加工导致管子内部产生残余应力,加剧了弯头脆性开裂的倾向。     

Structural regulation of electroplating sludge by a metal–organic framework synthesis method for an enhanced denitrification activity

Journal of Material Cycles and Waste Management - Electroplating sludge contained multi-metals and organics. In previous reports, electroplating sludges were usually recycled by direct calcination...     

中国省域森林公园旅游产业竞争力的时空演化特征及影响因素

分析我国各省森林公园旅游产业竞争力演变及其影响因素，有助于为处于不同发展阶段和不同发展水平的省份提供产业竞争力方面的指导。首先构建我国港澳台外31省（市、自治区）森林公园的旅游产业竞争力指标体系，然后计算各省旅游产业竞争力得分并分析其时空演变特征，最后采用分位数回归研究影响森林公园旅游产业竞争力空间差异的主要因素。结果表明：中国森林公园旅游产业平均竞争力值较低，区域差异较大，呈现东部向中西部递减的状态；2004~2014年期间西部各省森林公园旅游产业竞争力进步较小，主要原因是受到“短板效应”的制约，表现为西部各省在产业效益方面与东、中部省份存在较大差距；中国的森林公园存在东北和东南两个高层次旅游产业竞争力集聚中心，并存在逐渐向周边地区扩散，带动周边省份提升发展的趋势；回归表明，国家扶持力度、管理投入、资源禀赋、经济基础、品牌效应和交通便利性会在不同分位点上对各省森林公园旅游产业竞争力产生影响。森林公园旅游产业竞争力在不同分位点上影响因素的差异为有针对性的提高各地区竞争力提供了良好的参考。     

Road traffic injuries among riders of electric bike/electric moped in southern China

Objective: Electric bike/moped-related road traffic injuries have become a burgeoning public health problem in China. The objective of this study was to identify the prevalence and potential risk factors of electric bike/moped-related road traffic injuries among electric bike/moped riders in southern China.

Methods: A cross-sectional study was used to interview 3,151 electric bike/moped riders in southern China. Electric bike/moped-related road traffic injuries that occurred from July 2014 to June 2015 were investigated. Data were collected by face-to-face interviews and analyzed between July 2015 and June 2017.

Results: The prevalence of electric bike/moped-related road traffic injuries among the investigated riders was 15.99%. Electric bike/moped-related road traffic injuries were significantly associated with category of electric bike (adjusted odds ratio [AOR] = 1.36, 95% confidence interval [CI], 1.01–1.82), self-reported confusion (AOR = 1.77, 95% CI, 1.13–2.78), history of crashes (AOR = 6.14, 95% CI, 4.68–8.07), running red lights (AOR = 3.57, 95% CI, 2.42–5.25), carrying children while riding (AOR = 1.96, 95% CI, 1.37–2.85), carrying adults while riding (AOR = 1.68, 95% CI, 1.23–2.28), riding in the motor lane (AOR = 2.42, 95% CI, 1.05–3.93), and riding in the wrong traffic direction (AOR = 1.63, 95% CI, 1.13–2.35). In over 77.58% of electric bike/moped-related road traffic crashes, riders were determined by the police to be responsible for the crash. Major crash-causing factors included violating traffic signals or signs, careless riding, speeding, and riding in the wrong lane.

Conclusion: Traffic safety related to electric bikes/moped is becoming more problematic with growing popularity compared with other 2-wheeled vehicles. Programs need to be developed to prevent electric bike/moped-related road traffic injuries in this emerging country.     

行为经济学视角下矿工不安全行为仿真分析

为了分析影响矿工不安全行为决策的成本收益因素，扩展不安全行为的研究方向，基于行为经济学，构建矿工不安全行为决策模型，模型包括矿工属性、管理者属性以及矿工之间的交互影响规则。利用Netlogo工具进行仿真模拟，探讨不同影响因素对不安全行为产生的影响程度。结果表明:正向激励水平对抑制不安全行为效果显著，同时，维持合理的工作时间对保障安全生产意义重大，从而为煤矿企业控制不安全行为提供思路。     

吹扫捕集/气相色谱-原子荧光光度法测定土壤和沉积物中烷基汞

本文将原子荧光光谱检测技术与吹扫捕集/气相色谱检测技术联用,结合优化的碱性法消解前处理技术,建立了碱性法消解-吹扫捕集/气相色谱-原子荧光光谱(PT-GC-AFS)联用技术测定土壤和沉积物中烷基汞含量的方法,能够在一次分析中同时获得样品中甲基汞和乙基汞的含量.本文分别用酸性法和碱性法处理了沉积物标准样品ERM-CC580、沉积物实际样品和土壤实际样品,重点比较了本方法提出的碱性法消解和使用率较高的酸性法消解两种前处理方式.采用本方法处理实际样品进行了色谱分离研究,对低浓度的实际土壤样品进行了检出限实验,用3种不同浓度的沉积物和3种不同浓度的土壤样品验证了精密度,对沉积物标准参考物质ERM-CC580进行了测定,并用两种实际土壤样品和两种实际沉积物样品进行了加标回收率试验.实验表明,碱性法消解精密度和准确度优于酸性法消解,且步骤少、耗时短,使用的试剂种类少、毒性小,方法稳定性高、可操作性强,适用于分析测试实验室大量土壤/沉积物样品的烷基汞测定.采用碱性法消解土壤/沉积物样品,目标物实现完全分离,甲基汞、乙基汞的线性相关系数分别为0.9999、1.0000,最低检出限分别为0.02μg·kg~(-1)、0.10μg·kg~(-1)(取样量为0.50 g),样品分析甲基汞、乙基汞的RSD范围分别为1.0%—4.7%、2.5%—6.0%,加标回收率范围分别为85.1%—109%、90.3%—96.3%.     

典型有机磷酸酯阻燃剂分析方法研究进展

有机磷酸酯(OPEs)是一类重要的有机磷阻燃剂,近些年逐渐取代了溴代阻燃剂,广泛应用于各行各业,也因此导致在多种环境介质中有较高的暴露量和潜在风险。已有研究表明,OPEs具有一定的毒理效应,对人体及其他生物均有潜在危害。本文综述了近年来国内外OPEs的检测技术,详述了不同环境介质OPEs的前处理方法。结果表明,目前固相萃取(SPE)和固相微萃取(SPME)仍是水样前处理的主要方法;对于固体样品,加速溶剂萃取/加压液相萃取(ASE/PLE)和微波辅助萃取(MAE)应用较多;虽然大气样品仍以固体吸附剂方式为主,但已向在线一体化方向发展;而生物样品的前处理方法多与水样和固体样品方法相似;但是对于复杂环境介质中OPEs样品的前处理较为困难,方法有待改善;气相色谱-质谱联用(GC-MS)和气相色谱-氮磷检测器(GC-NPD)对弱极性和易挥发的OPEs分析效果好,而强极性和难挥发的OPEs多用液相色谱-质谱联用(LCMS);气相色谱-质谱串联(GC-MS/MS)、液相色谱-质谱串联(LC-MS/MS)和高效液相色谱-质谱串联(UPLC-MS/MS)等对多种复杂的环境介质中的OPEs均有较好的检测分析效果,但并未普及。最后,对OPEs分析测试方法的发展趋势提出了展望。     

Diffusive gradients in thin films using molecularly imprinted polymer binding gels for in situ measurements of antibiotics in urban wastewaters

• Selective molecularly imprinted polymer (MIP) binding gel was prepared. • MIP-DGT showed excellent uptake performance for antibiotics. • In situ measurement of antibiotics in wastewaters via MIP-DGT was developed. • The MIP-DGT method was robust, reliable, and highly sensitive. Urban wastewater is one of main sources for the introduction of antibiotics into the environment. Monitoring the concentrations of antibiotics in wastewater is necessary for estimating the amount of antibiotics discharged into the environment through urban wastewater treatment systems. In this study, we report a novel diffusive gradient in thin films (DGT) method based on molecularly imprinted polymers (MIPs) for in situ measurement of two typical antibiotics, fluoroquinolones (FQs) and sulfonamides (SAs) in urban wastewater. MIPs show specific adsorption toward their templates and their structural analogs, resulting in the selective uptake of the two target antibiotics during MIP-DGT deployment. The uptake performance of the MIP-DGTs was evaluated in the laboratory and was relatively independent of solution pH (4.0–9.0), ionic strength (1–750 mmol/L), and dissolved organic matter (DOM, 0–20 mg/L). MIP-DGT samplers were tested in the effluent of an urban wastewater treatment plant for field trials, where three SA (sulfamethoxazole, sulfapyridine, and trimethoprim) and one FQ (ofloxacin) antibiotics were detected, with concentrations ranging from 25.50 to 117.58 ng/L, which are consistent with the results measured by grab sampling. The total removal efficiency of the antibiotics was 80.1% by the treatment plant. This study demonstrates that MIP-DGT is an effective tool for in situ monitoring of trace antibiotics in complex urban wastewaters.     

Evaluating provincial eco-efficiency in China: an improved network data envelopment analysis model with undesirable output

Environmental Science and Pollution Research - In this study, an improved matrix-type network data envelopment analysis (NDEA) model with undesirable output was developed to evaluate the...     

N2 fixation in urbanization area rivers: spatial-temporal variations and influencing factors

Environmental Science and Pollution Research - While nitrogen (N2) fixation is an important process in nitrogen (N) biogeochemical cycling, supplying a significant portion of the N in natural...